CobaltMaghrebV1, France, Analysis, bibRecord, 000030

catena-Poly[bis(μ3-2-phenylacetato-κ3O,O′:O)bis(μ2-2-phenylacetato-κ2O:O′)dicopper(II)(Cu—Cu)]

Identifieur interne : 000030 ( France/Analysis ); précédent : 000029; suivant : 000031

catena-Poly[bis(μ3-2-phenylacetato-κ3O,O′:O)bis(μ2-2-phenylacetato-κ2O:O′)dicopper(II)(Cu—Cu)]

Auteurs : Meriem Benslimane [Algérie] ; Yasmine Kheira Redjel [Algérie] ; Hocine Merazig [Algérie] ; Jean-Claude Daran [France]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.

RBID : PMC:3772427

Abstract

The title polymeric compound, [Cu₂(C₈H₇O₂)₄]_n, was synthesized by the reaction of copper acetate with aqueous phenylacetic acid. The unique Cu^II atom is coordinated by five O atoms from the carboxylate groups of phenylacetate ligands, and the strongly distorted octahedral coordination environment is completed by a Cu—Cu bond of 2.581 (2) Å, at whose mid-point is located an inversion centre. The crystal structure consists of infinite polymeric linear chains of Cu²⁺ ions, running along [100], linked by bridging phenylacetate groups.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772427

DOI: 10.1107/S160053681301581X
PubMed: 24046570
PubMed Central: 3772427

Affiliations:

Algérie, France

Links to Exploration step

PMC:3772427

Le document en format XML

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-Poly[bis(μ<sub>3</sub>
-2-phenylacetato-κ<sup>3</sup>
<italic>O</italic>
,<italic>O</italic>
′:<italic>O</italic>
)bis(μ<sub>2</sub>
-2-phenylacetato-κ<sup>2</sup>
<italic>O</italic>
:<italic>O</italic>
′)dicopper(II)(<italic>Cu</italic>
—<italic>Cu</italic>
)]</title>
<author><name sortKey="Benslimane, Meriem" sort="Benslimane, Meriem" uniqKey="Benslimane M" first="Meriem" last="Benslimane">Meriem Benslimane</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Redjel, Yasmine Kheira" sort="Redjel, Yasmine Kheira" uniqKey="Redjel Y" first="Yasmine Kheira" last="Redjel">Yasmine Kheira Redjel</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
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<author><name sortKey="Daran, Jean Claude" sort="Daran, Jean Claude" uniqKey="Daran J" first="Jean-Claude" last="Daran">Jean-Claude Daran</name>
<affiliation wicri:level="1"><nlm:aff id="b">Laboratoire de Chimie de Coordination, UPR-CNRS 8241, 205 route de Narbonne, 31077 Toulouse Cedex 4,<country>France</country>
</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
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<idno type="pmc">3772427</idno>
<idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3772427</idno>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main"><italic>catena</italic>
-Poly[bis(μ<sub>3</sub>
-2-phenylacetato-κ<sup>3</sup>
<italic>O</italic>
,<italic>O</italic>
′:<italic>O</italic>
)bis(μ<sub>2</sub>
-2-phenylacetato-κ<sup>2</sup>
<italic>O</italic>
:<italic>O</italic>
′)dicopper(II)(<italic>Cu</italic>
—<italic>Cu</italic>
)]</title>
<author><name sortKey="Benslimane, Meriem" sort="Benslimane, Meriem" uniqKey="Benslimane M" first="Meriem" last="Benslimane">Meriem Benslimane</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<author><name sortKey="Redjel, Yasmine Kheira" sort="Redjel, Yasmine Kheira" uniqKey="Redjel Y" first="Yasmine Kheira" last="Redjel">Yasmine Kheira Redjel</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name>
<affiliation wicri:level="1"><nlm:aff id="a">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Daran, Jean Claude" sort="Daran, Jean Claude" uniqKey="Daran J" first="Jean-Claude" last="Daran">Jean-Claude Daran</name>
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</nlm:aff>
<country xml:lang="fr">France</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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</analytic>
<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
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<front><div type="abstract" xml:lang="en"><p>The title polymeric compound, [Cu<sub>2</sub>
(C<sub>8</sub>
H<sub>7</sub>
O<sub>2</sub>
)<sub>4</sub>
]<sub><italic>n</italic>
</sub>
, was synthesized by the reaction of copper acetate with aqueous phenylacetic acid. The unique Cu<sup>II</sup>
 atom is coordinated by five O atoms from the carboxylate groups of phenylacetate ligands, and the strongly distorted octahedral coordination environment is completed by a Cu—Cu bond of 2.581 (2) Å, at whose mid-point is located an inversion centre. The crystal structure consists of infinite polymeric linear chains of Cu<sup>2+</sup>
 ions, running along [100], linked by bridging phenylacetate groups.</p>
</div>
</front>
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<affiliations><list><country><li>Algérie</li>
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<tree><country name="Algérie"><noRegion><name sortKey="Benslimane, Meriem" sort="Benslimane, Meriem" uniqKey="Benslimane M" first="Meriem" last="Benslimane">Meriem Benslimane</name>
</noRegion>
<name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name>
<name sortKey="Redjel, Yasmine Kheira" sort="Redjel, Yasmine Kheira" uniqKey="Redjel Y" first="Yasmine Kheira" last="Redjel">Yasmine Kheira Redjel</name>
</country>
<country name="France"><noRegion><name sortKey="Daran, Jean Claude" sort="Daran, Jean Claude" uniqKey="Daran J" first="Jean-Claude" last="Daran">Jean-Claude Daran</name>
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</record>

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   |texte=   catena-Poly[bis(μ3-2-phenylacetato-κ3O,O′:O)bis(μ2-2-phenylacetato-κ2O:O′)dicopper(II)(Cu—Cu)]
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Serveur d'exploration sur le cobalt au Maghreb

catena-Poly[bis(μ3-2-phenylacetato-κ3O,O′:O)bis(μ2-2-phenylacetato-κ2O:O′)dicopper(II)(Cu—Cu)]

catena-Poly[bis(μ3-2-phenylacetato-κ3O,O′:O)bis(μ2-2-phenylacetato-κ2O:O′)dicopper(II)(Cu—Cu)]

Source :

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

	Serveur d'exploration sur le cobalt au Maghreb
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le cobalt au Maghreb

catena-Poly[bis­(μ3-2-phenyl­acetato-κ3O,O′:O)bis­(μ2-2-phenyl­acetato-κ2O:O′)dicopper(II)(Cu—Cu)]

catena-Poly[bis­(μ3-2-phenyl­acetato-κ3O,O′:O)bis­(μ2-2-phenyl­acetato-κ2O:O′)dicopper(II)(Cu—Cu)]

Source :

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

catena-Poly[bis(μ3-2-phenylacetato-κ3O,O′:O)bis(μ2-2-phenylacetato-κ2O:O′)dicopper(II)(Cu—Cu)]

catena-Poly[bis(μ3-2-phenylacetato-κ3O,O′:O)bis(μ2-2-phenylacetato-κ2O:O′)dicopper(II)(Cu—Cu)]